2-Methyl-3-nitrobenzyl cyanide

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2-Methyl-3-nitro­benzyl cyanide

The title compound, C(9)H(8)N(2)O, was prepared from o-xylene by nitration, oxidation, hydrolysis, reduction, chlorination and cyanation. There are two mol-ecules in the asymmetric unit with a dihedral angle of 20.15 (7)° between their aromatic rings.

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3-Carbamoyl-1-(2-nitrobenzyl)pyridin­ium bromide

In the title compound, C(13)H(12)N(3)O(3) (+)·Br(-), the benzene and pyridinium rings form a dihedral angle of 82.0 (1)°. In the crystal, N-H⋯Br and N-H⋯O hydrogen bonds link the components into chains along [001]. In addition, weak C-H⋯O and C-H⋯Br hydrogen bonds are observed.

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2-Methyl-3-nitro­benzonitrile

The asymmetric unit of the title compound, C(8)H(6)N(2)O(2), contains two independent mol-ecules, the aromatic rings of which are oriented at a dihedral angle of 1.68 (3)°. Intra-molecular C-H⋯O hydrogen bonds result in the formation of two non-planar six-membered rings, which adopt envelope and twisted conformations. In the crystal structure, inter-molecular C-H⋯O hydrogen bonds link the mol-e...

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Photochemical reaction mechanisms of 2-nitrobenzyl compounds: methyl ethers and caged ATP.

The mechanism of methanol photorelease from 2-nitrobenzyl methyl ether (1) and 1-(2-nitrophenyl)ethyl methyl ether (2), and of ATP release from adenosine-5'-triphosphate-[P(3)-(1-(2-nitrophenyl)ethyl)] ester ('caged ATP', 3) was studied in various solvents by laser flash photolysis with UV-vis and IR detection. In addition to the well-known primary aci-nitro transients (A, lambda(max) approxima...

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2-Methyl-N-[(3-methyl-2-pyrid­yl)carbamothio­yl]benzamide

In the title compound, C(15)H(15)N(3)OS, the thio-urea group is stabilized by an intra-molecular hydrogen bond between the carbonyl O atom and the thio-amide group. A C-H⋯N intramolecular hydrogen bond is also present. Mol-ecules are linked by inter-molecular N-H⋯O and C-H⋯S hydrogen bonds.

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2009

ISSN: 1600-5368

DOI: 10.1107/s1600536809008484